How can I print all usernames and passwords?

In the past, when I had a stand alone membership, I would make a copy of my usernames and passwords to put in my safe box. I no longer have the stand alone membership but the subscription. I thought I would continue to make a copy of my usernames and passwords to keep in my safe box. Frankly, this is for my wife just in case.

For security purposes, my vault is always encrypted, right? Whether I export or print anything doesn't change that I hope. I would hope nothing would expose the information in my vault. Please confirm that as I thought that was the major premise of 1 Password.